N-donor co-ligands driven two new Co(II)-coordination polymers with bi- and trinuclear units: Crystal structures, and magnetic properties

Zhi-Hang Zhou, Min-Le Han, Ya-Pan Wu, Wen-Wen Dong, Dong-Sheng Li,* Jack Y. Lu

Two new Co(II) coordination polymers with bi- and trinuclear units have been obtained. 1 shows a binodal (4,6)-connected fsc net with a (44·610·8)(44·62) topology and antiferromagnetic interactions between the adjacent Co(II) ions, while 2 is a binodal (5,7)-connected 3D network with unusual (3.46.52.6)(32.46.57.65.7) topology and a ferromagnetic system.

J. Solid State Chem.2016,242, 207–211.